The Development of NEI’s Anti-Ice Coating Technology for the Aerospace Industry
A Case Study of NANOMYTE® SuperAi from Concept to Implementation
The leading edge of the wing is where icing occurs
A manufacturer of de-icing systems brought up the idea of combining an active de-icing system with a coating that easily sheds ice. Ice formation on the leading edge of an aircraft is a common aviation danger, playing a key role in several catastrophic accidents over the years that have killed people and destroyed aircrafts. All commercial aircraft have a built-in ice protection system, which could be either a thermal, thermal-mechanical, electro-mechanical, or pneumatic system. A common issue with de-icing devices is that they consume substantial power. Aircraft generally look to reduce power consumption, and with the advent of battery-powered aircraft, mechanisms or features that reduce power consumption are critically important. The aspect of reduced power is also relevant for battery powered drones. Applying a passive anti-ice coating that functions synergistically with the active de-icing device is an attractive approach. The advantages are reduced power consumption, improved service life of mechanical components, lighter electronics and extra protection in case of failure of active device.
The challenge presented to the engineers and scientists at NEI Corporation was to develop and demonstrate a coating that exhibits durable anti-ice performance and satisfactory wear and erosion resistance. More importantly, it needed to be practical for retrofitting in-service aircraft as well as be used by OEMs. In order to address the need, NEI developed its NANOMYTE® SuperAiTM coating technology to have the following features:
- Extremely lubricating surface
- Superior ice adhesion reduction factor
- Thin coating (< 1 mil or 25 microns), providing a light weight solution
- Durable anti-ice performance, suitable for permanent application
- Room temperature cure
- Easy application by spraying, dipping, or brushing
The development of the SuperAiTM coating started after numerous discussions with engineers at a major low-power ice protection system manufacturer. They brought to our attention the two basic technical requirements for an anti-ice coating to be applied on their de-icing systems, i.e., lower ice adhesion and durable anti-ice performance. We demonstrated both attributes after extensive experiments in NEI’s laboratory and iterative testing at an icing wind tunnel facility with prototype de-icing devices. The ice adhesion measurements taken at NEI were corroborated by work done at the Penn State Adverse Environment Rotor Test Stand (AERTS) facility, which repeatedly showed an ice adhesion strength as low as ~1.8 psi for the SuperAiTM coated aluminum substrate – this represents an 80% reduction compared to an uncoated polished aluminum substrate (Figure 1). Figure 1 shows a pure adhesive failure when an ice column was pulled off the SuperAiTM coated substrate. In contrast, a cohesive failure of ice is seen for the uncoated aluminum substrate.
Figure 1: Ice adhesion strength and locus of failure of SuperAiTM coated aluminum as compared to those of uncoated polished aluminum
To demonstrate the enhanced de-icing efficiency of a de-icing device with the use of SuperAiTM, coated prototypes of electro-mechanical and thermal-mechanical expulsion de-icing systems were tested in an icing tunnel under simulated in-flight icing conditions at our collaborator’s facility. Figure 2 shows the SuperAiTM coated leading edge being assembled with the thermal-mechanical expulsion de-icing system. We have repeatedly demonstrated that improved de-icing efficiency, along with a 45-70% reduction in power consumption of the active de-icing systems could be achieved with the use of the newly developed anti-ice coating (Figure 3).
Figure 2: Installation of leading edge and thermal-mechanical expulsion de-icing system assembly.
Figure 3: Snapshots taken from recording of icing tunnel test showing complete de-icing on coated leading edge (bottom) and no de-icing on uncoated leading edge (top), at power consumption level 70% lower than that of the nominal power needed for a regular functional uncoated de-icing system.
Abrasion resistance is of great importance for the targeted application. Figure 4 shows that the SuperAi coating was barely scratched at the wear track after 200 cycles of Taber abrasion. Note that the CS-10F Calibrase® wheel used in the test is composed of a binder and abrasive particles such as aluminum oxide and silicon carbide. The testing conditions simulate normal service abrasion and wear. Further, the contact angle at the wear track was measured to be 103° (vs. 105° of fresh unabraded surface), indicating that the hydrophobicity of the surface was minimally affected by the abrasion. The ice adhesion measurement at the wear track showed that the coating remained highly icephobic after 200 cycles of Taber abrasion (Figure 5).
Figure 4: Optical micrograph taken at the wear track after Taber test showing excellent abrasion resistance of the SuperAiTM coating.
Other important aspects of an anti-ice coating for aircraft include its ability to resist rain erosion, chemical and solvent resistance, resistance to icing-deicing cycles and weatherability. These aspects were investigated with various durability tests. As can be seen in Figure 5, the SuperAiTM coating could survive repeated icing-deicing cycles. There was little change in ice adhesion after immersion in jet fuel, Skydrol® (an aviation hydraulic fluid), and water for an extended period of time. Further, the ice adhesion strength was minimally affected by abrasion, high-pressure power wash and UV-Con exposure.
Figure 5: Ice adhesion results for SuperAiTM after various durability tests.
In summary, we were able to address an important need in the industry, using a disciplined and focused product development effort. The case study presented here is representative of the application-driven coatings development effort we undertake to address a problem or an opportunity. We work directly with customers and seek to develop, demonstrate, and implement a solution.
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Gains in productivity and efficiency are possible when a coating or surface treatment provides functionalities beyond the usual protective and aesthetic properties. This realization has sparked great interest in functional coatings in recent years for applications that traditionally have not used paints or coatings. A good example is the use of anti-ice coatings on power transmission lines. Mitigating ice accumulation will help prevent power outages, which has a tangible and beneficial economic impact. Another example is the use of a surface treatment to increase the efficiency of power generation turbines.
More often than not, many of the functionalities mentioned above need to be integrated into a single coating or surface treatment. For example, a transparent coating that resists finger printing also needs to be scratch resistant and durable. A coating that prevents fogging in eyewear and other transparent surfaces must also be durable and resistant to chemicals. Further, in order to meet the cost criteria, application of the coating must be compatible with conventional coating methods such as spray, dip, brush or flow. Over the past few years, NEI Corporation’s concerted efforts to develop and implement practical, multi-functional coatings are now coming to fruition.
Backed by a bevy of issued and pending patents, NEI has introduced an array of coating products under the registered trade name NANOMYTE®. For example, 
Self-healing principles can also be applied to surface treatments of metals, whereby the pretreatments can mimic the performance of chromate conversion coatings. To this end, NEI has developed a series of pretreatments for different metals where a chemical self-healing mechanism imparts corrosion resistance. For example, 
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